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Product Name: ESSOTRANS EXTRA

Revision Date: 22 Feb 2010

Page of

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MATERIAL SAFETY DATA SHEET


SECTION 1

PRODUCT AND COMPANY IDENTIFICATION


PRODUCT

Product Name: ESSOTRANS EXTRA

Product Description: Base Oil and Additives

MSDS Number: 13644

Intended Use: Manual transmission fluid
COMPANY IDENTIFICATION

Supplier: Imperial Oil Products Division

240 4th Avenue

Calgary, ALBERTA. T2P 3M9 Canada

24 Hour Environmental / Health Emergency Telephone

519-339-2145

Transportation Emergency Phone Number

519-339-2145

Product Technical Information

1-800-268-3183

Supplier General Contact

1-800-567-3776


SECTION 2

COMPOSITION / INFORMATION ON INGREDIENTS


No Reportable Hazardous Substance(s) or Complex Substance(s).

SECTION 3

HAZARDS IDENTIFICATION

This material is not considered to be hazardous according to regulatory guidelines see Section 15.

HEALTH EFFECTS

Low order of toxicity. Excessive exposure may result in eye, skin, or respiratory irritation. High-pressure injection under skin may cause serious damage.


NFPA Hazard ID:

Health: 0

Flammability: 1

Reactivity: 0

HMIS Hazard ID:

Health: 0

Flammability: 1

Reactivity: 0



NOTE: This material should not be used for any other purpose than the intended use in Section 1 without expert advice. Health studies have shown that chemical exposure may cause potential human health risks which may vary from person to person.



SECTION 4

FIRST AID MEASURES


INHALATION

Remove from further exposure. For those providing assistance, avoid exposure to yourself or others. Use adequate respiratory protection. If respiratory irritation, dizziness, nausea, or unconsciousness occurs, seek immediate medical assistance. If breathing has stopped, assist ventilation with a mechanical device or use mouth-to-mouth resuscitation.
SKIN CONTACT

Wash contact areas with soap and water. If product is injected into or under the skin, or into any part of the body, regardless of the appearance of the wound or its size, the individual should be evaluated immediately by a physician as a surgical emergency. Even though initial symptoms from high pressure injection may be minimal or absent, early surgical treatment within the first few hours may significantly reduce the ultimate extent of injury.
EYE CONTACT

Flush thoroughly with water. If irritation occurs, get medical assistance.
INGESTION

First aid is normally not required. Seek medical attention if discomfort occurs.


SECTION 5

FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA

Appropriate Extinguishing Media: Use water fog, foam, dry chemical or carbon dioxide (CO2) to extinguish flames.
Inappropriate Extinguishing Media: Straight streams of water
FIRE FIGHTING

Fire Fighting Instructions: Evacuate area. Prevent run-off from fire control or dilution from entering streams, sewers or drinking water supply. Fire-fighters should use standard protective equipment and in enclosed spaces, self-contained breathing apparatus (SCBA). Use water spray to cool fire exposed surfaces and to protect personnel.
Hazardous Combustion Products: Smoke, Fume, Aldehydes, Sulphur oxides, Incomplete combustion products, Oxides of carbon
FLAMMABILITY PROPERTIES

Flash Point [Method]: 160C (320F) [ ASTM D-92]

Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0

Autoignition Temperature: N/D


SECTION 6

ACCIDENTAL RELEASE MEASURES



NOTIFICATION PROCEDURES

In the event of a spill or accidental release, notify relevant authorities in accordance with all applicable regulations.


SPILL MANAGEMENT

Land Spill: Stop leak if you can do so without risk. Recover by pumping or with suitable absorbent.
Water Spill: Stop leak if you can do so without risk. Confine the spill immediately with booms. Warn other shipping. Remove from the surface by skimming or with suitable absorbents. Seek the advice of a specialist before using dispersants.
Water spill and land spill recommendations are based on the most likely spill scenario for this material; however, geographic conditions, wind, temperature, (and in the case of a water spill) wave and current direction and speed may greatly influence the appropriate action to be taken. For this reason, local experts should be consulted. Note: Local regulations may prescribe or limit action to be taken.
ENVIRONMENTAL PRECAUTIONS

Large Spills: Dyke far ahead of liquid spill for later recovery and disposal. Prevent entry into waterways, sewers, basements or confined areas.



SECTION 7

HANDLING AND STORAGE


HANDLING

Prevent small spills and leakage to avoid slip hazard. Material can accumulate static charges which may cause an electrical spark (ignition source). When the material is handled in bulk, an electrical spark could ignite any flammable vapors from liquids or residues that may be present (e.g., during switch-loading operations). Use proper bonding and/or earthing procedures. However, bonding and earthing may not eliminate the hazard from static accumulation. Consult local applicable standards for guidance. Additional references include American Petroleum Institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practice on Static Electricity) or CENELEC CLC/TR 50404 (Electrostatics - Code of practice for the avoidance of hazards due to static electricity).
Static Accumulator: This material is a static accumulator.
STORAGE

The container choice, for example storage vessel, may effect static accumulation and dissipation. Do not store in open or unlabelled containers.


SECTION 8

EXPOSURE CONTROLS / PERSONAL PROTECTION


Substance Name

Form

Limit/Standard

Note

Source

HYDROTREATED LIGHT NAPHTHENIC DISTILLATE (PETROLEUM)

Mist.

STEL

10 mg/m3







ACGIH

HYDROTREATED LIGHT NAPHTHENIC DISTILLATE (PETROLEUM)

Mist.

TWA

5 mg/m3







ACGIH

Exposure limits/standards for materials that can be formed when handling this product: When mists / aerosols can occur, the following are recommended: 5 mg/m³ - ACGIH TLV, 10 mg/m³ - ACGIH STEL.


NOTE: Limits/standards shown for guidance only. Follow applicable regulations.
ENGINEERING CONTROLS
The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Control measures to consider:

No special requirements under ordinary conditions of use and with adequate ventilation.
PERSONAL PROTECTION

Personal protective equipment selections vary based on potential exposure conditions such as applications, handling practices, concentration and ventilation. Information on the selection of protective equipment for use with this material, as provided below, is based upon intended, normal usage.
Respiratory Protection: If engineering controls do not maintain airborne contaminant concentrations at a level which is adequate to protect worker health, an approved respirator may be appropriate. Respirator selection, use, and maintenance must be in accordance with regulatory requirements, if applicable. Types of respirators to be considered for this material include:

No special requirements under ordinary conditions of use and with adequate ventilation.
For high airborne concentrations, use an approved supplied-air respirator, operated in positive pressure mode. Supplied air respirators with an escape bottle may be appropriate when oxygen levels are inadequate, gas/vapour warning properties are poor, or if air purifying filter capacity/rating may be exceeded.
Hand Protection: Any specific glove information provided is based on published literature and glove manufacturer data. Glove suitability and breakthrough time will differ depending on the specific use conditions. Contact the glove manufacturer for specific advice on glove selection and breakthrough times for your use conditions. Inspect and replace worn or damaged gloves. The types of gloves to be considered for this material include:

No protection is ordinarily required under normal conditions of use.
Eye Protection: If contact is likely, safety glasses with side shields are recommended.
Skin and Body Protection: Any specific clothing information provided is based on published literature or manufacturer data. The types of clothing to be considered for this material include:

No skin protection is ordinarily required under normal conditions of use. In accordance with good industrial hygiene practices, precautions should be taken to avoid skin contact.
Specific Hygiene Measures: Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practise good housekeeping.


ENVIRONMENTAL CONTROLS

See Sections 6, 7, 12, 13.


SECTION 9

PHYSICAL AND CHEMICAL PROPERTIES


Typical physical and chemical properties are given below. Consult the Supplier in Section 1 for additional data.
GENERAL INFORMATION

Physical State: Liquid

Colour: Amber

Odour: Characteristic

Odour Threshold: N/D
IMPORTANT HEALTH, SAFETY, AND ENVIRONMENTAL INFORMATION

Relative Density (at 15 C): 0.87

Flash Point [Method]: 160C (320F) [ ASTM D-92]

Flammable Limits (Approximate volume % in air): LEL: 0.9 UEL: 7.0

Autoignition Temperature: N/D

Boiling Point / Range: N/D

Vapour Density (Air = 1): N/D

Vapour Pressure: < 0.1 kPa (0.75 mm Hg) at 20°C

Evaporation Rate (n-butyl acetate = 1): < 0.1

pH: N/A

Log Pow (n-Octanol/Water Partition Coefficient): > 3.5

Solubility in Water: Negligible

Viscosity: 34 cSt (34 mm2/sec) at 40°C | 7.4 cSt (7.4 mm2/sec) at 100C

Oxidizing Properties: See Hazards Identification Section.
OTHER INFORMATION

Freezing Point: N/D

Melting Point: N/A

Pour Point: -51°C (-60°F)

DMSO Extract (mineral oil only), IP-346: < 3 %wt


SECTION 10

STABILITY AND REACTIVITY


STABILITY: Material is stable under normal conditions.
CONDITIONS TO AVOID: Excessive heat. High energy sources of ignition.
MATERIALS TO AVOID: Strong oxidizers
HAZARDOUS DECOMPOSITION PRODUCTS: Material does not decompose at ambient temperatures.
HAZARDOUS POLYMERIZATION: Will not occur.


SECTION 11

TOXICOLOGICAL INFORMATION


ACUTE TOXICITY

Route of Exposure

Conclusion / Remarks

Inhalation




Toxicity (Rat): LC50 > 5000 mg/m3

Minimally Toxic. Based on test data for structurally similar materials.

Irritation: No end point data.

Negligible hazard at ambient/normal handling temperatures. Based on assessment of the components.







Ingestion




Toxicity (Rat): LD50 > 5000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.







Skin




Toxicity (Rabbit): LD50 > 5000 mg/kg

Minimally Toxic. Based on test data for structurally similar materials.

Irritation (Rabbit): Data available.

Negligible irritation to skin at ambient temperatures. Based on test data for structurally similar materials.







Eye




Irritation (Rabbit): Data available.

May cause mild, short-lasting discomfort to eyes. Based on test data for structurally similar materials.


CHRONIC/OTHER EFFECTS

For the product itself:

Repeated and/or prolonged exposure may cause irritation to the skin, eyes, or respiratory tract.

Contains:

Base oil severely refined: Not carcinogenic in animal studies. Representative material passes IP-346, Modified Ames test, and/or other screening tests. Dermal and inhalation studies showed minimal effects; lung non-specific infiltration of immune cells, oil deposition and minimal granuloma formation. Not sensitising in test animals.
Additional information is available by request.

CMR Status: None.



Chemical Name

CAS Number

List Citations

HYDROTREATED LIGHT NAPHTHENIC DISTILLATE (PETROLEUM)

64742-53-6

4


--REGULATORY LISTS SEARCHED--

1 = IARC 1

3 = IARC 2B

5 = ACGIH A1

2 = IARC 2A

4 = ACGIH ALL

6 = ACGIH A2


SECTION 12

ECOLOGICAL INFORMATION


The information given is based on data available for the material, the components of the material, and similar materials.
ECOTOXICITY

Material -- Expected to be harmful to aquatic organisms. May cause long-term adverse effects in the aquatic environment.
MOBILITY

Base oil component -- Low solubility and floats and is expected to migrate from water to the land. Expected to partition to sediment and wastewater solids.
PERSISTENCE AND DEGRADABILITY

Biodegradation:

Base oil component -- Expected to be inherently biodegradable
BIOACCUMULATION POTENTIAL

Base oil component -- Has the potential to bioaccumulate, however metabolism or physical properties may reduce the bioconcentration or limit bioavailability.



SECTION 13

DISPOSAL CONSIDERATIONS



Disposal recommendations based on material as supplied. Disposal must be in accordance with current applicable laws and regulations, and material characteristics at time of disposal.

DISPOSAL RECOMMENDATIONS

Product is suitable for burning in an enclosed controlled burner for fuel value or disposal by supervised incineration at very high temperatures to prevent formation of undesirable combustion products.

REGULATORY DISPOSAL INFORMATION

Empty Container Warning Empty Container Warning (where applicable): Empty containers may contain residue and can be dangerous. Do not attempt to refill or clean containers without proper instructions. Empty drums should be completely drained and safely stored until appropriately reconditioned or disposed. Empty containers should be taken for recycling, recovery, or disposal through suitably qualified or licensed contractor and in accordance with governmental regulations. DO NOT PRESSURISE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE SUCH CONTAINERS TO HEAT, FLAME, SPARKS, STATIC ELECTRICITY, OR OTHER SOURCES OF IGNITION. THEY MAY EXPLODE AND CAUSE INJURY OR DEATH.


SECTION 14

TRANSPORT INFORMATION


LAND (TDG): Not Regulated for Land Transport


LAND (DOT): Not Regulated for Land Transport


SEA (IMDG): Not Regulated for Sea Transport according to IMDG-Code


AIR (IATA): Not Regulated for Air Transport


SECTION 15

REGULATORY INFORMATION


WHMIS Classification: Not controlled
This product has been classified in accordance with hazard criteria of the Controlled Products Regulations and the (M)SDS contains all the information required by the Controlled Products Regulations.
CEPA: All components of this material are either on the Canadian Domestic Substances List (DSL), exempt, or have been notified under CEPA.
NATIONAL CHEMICAL INVENTORY LISTING: DSL, TSCA

The Following Ingredients are Cited on the Lists Below:


Chemical Name

CAS Number

List Citations

Nonyl Phenyl Ethoxylate

9016-45-9

6



--REGULATORY LISTS SEARCHED--

1 = TSCA 4

3 = TSCA 5e

5 = TSCA 12b

2 = TSCA 5a2

4 = TSCA 6

6 = NPRI



SECTION 16

OTHER INFORMATION

N/D = Not determined, N/A = Not applicable


THIS SAFETY DATA SHEET CONTAINS THE FOLLOWING REVISIONS:

Revision Changes:

Section 04: First Aid Eye - Header was modified.

Section 04: First Aid Ingestion - Header was modified.

Section 06: Notification Procedures - Header was modified.

Section 11: Acute Toxicity Table Header was modified.

Section 11: Inhalation - Header was modified.

Section 09: Evaporation Rate - Header was modified.

Section 09: Vapour Pressure - Header was modified.

Section 07: Handling and Storage-Handling was modified.

Section 07: Handling and Storage-Storage Phrases was modified.

Section 11: Inhalation Lethality Test Data was modified.

Section 05: Hazardous Combustion Products was modified.

Section 06: Accidental Release- Spill Management- Water was modified.

Section 09 Viscosity was modified.

Section 09 Viscosity was modified.

Section 14: Sea (IMDG) - Header was modified.

Section 14: Air (IATA) - Header was modified.

Section 14: LAND (TDG) - Header was modified.

Section 14: LAND (DOT) - Header was modified.

Section 14: LAND (DOT) - Default was modified.

Section 14: LAND (TDG) Default was modified.

Section 14: Sea (IMDG) - Default was modified.

Section 14: Air (IATA) - Default was modified.

Section 15: National Chemical Inventory Listing - Header was modified.

Hazard Identification: Hazards Note was modified.

Section 16: CA Prepared by - Header was modified.

Section 09: Oxidizing Properties was modified.

Section 15: List Citation Table - Header was modified.

Section 13: Regulatory Disposal Information - Header was modified.

Section 15: Canadian List Citations Table was added.

Section 15: Chemical Name - Header was added.

Section 15: CAS Number - Header was added.

Section 15: List Citations -Header was added.

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WHMIS Classification: Not controlled


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The information and recommendations contained herein are, to the best of Imperial Oil's knowledge and belief, accurate and reliable as of the date issued. Imperial Oil assumes no responsibility for accuracy of information unless the document is the most current available from an official Imperial Oil distribution system. The information and recommendations are offered for the user's consideration and examination, and it is the user's responsibility to satisfy itself that they are suitable and complete for its particular use. If buyer repackages this product, legal counsel should be consulted to insure proper health, safety and other necessary information is included on the container. Appropriate warnings and safe-handling procedures should be provided to handlers and users. Alteration of this document is strictly prohibited. Except to the extent required by law, republication or retransmission of this document, in whole or in part, is not permitted.

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DGN: 5011741 (1002750)

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Copyright 2002 Imperial Oil Limited, All rights reserved
Prepared by: Imperial Oil Limited, IH and Product Safety



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